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Oyo Boy Sotto - After a six-month courtship, Curtis entered into a two-year relationship with now ex-boyfriend Oyo Boy Sotto, son of well-known showbiz personalities Vic Sotto and Dina Bonnevie and an actor himself. Curtis describes her relationship with Sotto as her first brush with genuine love, saying of him: "He was the one who I really loved." By June 2003, the relationship was officially over. In a later interview, Sotto blamed "immaturity and possessiveness" as the reasons their relationship did not work out.
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Richard Gutierrez - Curtis also had a well-publicized relationship with fellow actor Richard Gutierrez in 2004. They had been together for 1 year.The two had worked together on the TV shows Nuts Entertainment and Love to Love.
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Paolo Araneta - Curtis later became involved with Paolo Araneta, a relationship that lasted for two years. By January 2006, however, the local entertainment press confirmed that Curtis and Araneta had parted ways.
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Luis Manzano - The two are mostly paired. They were linked to each other but they admitted that they are just good friends. They are good friends for 8 yrs. already.
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Sam Milby - In 2006, while taping Maging Sino Ka Man, Sam Milby and Anne Curtis had mutual understandings that led to dating.There were many speculations that they were together but they kept on denying.They were mostly seen together. Sam and Anne admitted that they were together before but they broke because they want to have a good relationship with God first. Until in 2007, they cleared all the rumors. Both of them admitted that they reunited but they were just exclusively dating but they weren't together. They were really sweet with each other. The evidences were witnessed during the Star Magic ball 2008. They were known the hottest couple because the two stars are 2 of the hottest stars nowadays. Unfortunately, last September 2008, it was rumored that they broke up already. Anne said in The Buzz interview that it was Sam who finished their relationship. They had been together for 2 yrs.
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Erwan Heussaff - Rumors had it that he was the one Anne dated when she had her Europe Vacation back in 2009. He is a business man, chef and brother of rising Survivor Celebrity Edition star Solenn Heasaff. Anne announced that it was in 2010 that they started to be exclusively dating. There's really not a lot of news with this couple because she decided to make their relationship to be kept from the lime light.